AXAF Project Science:
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The following table contains x-ray line energies and linewidths, including those for the elements and compounds that comprise the XSS EIPS targets. The line energies were taken from Bearden (1967). Krause and Oliver (1979) have provided semi-empirical linewidths based on the sum of the level widths involved in the particular line transitions. These estimates, however, do not include line-broadening caused by collective effects expected in the solid targets of the EIPS. Salem and Lee (1976) provided a least-squares fit to the existing linewidth data for K and L lines, for elements of even values of Z from 20 through 96, including solid-state line-broadening. Since this work there have been additional precision measurements of linewidths (many of these are for Z < 40) which we use to supplant earlier data (e.g. Parratt (1933); Allison, etc.) used in Salem and Lee's fit that may have systematic errors, or did not quote an uncertainty in their stated value. In this table we provide the precision measured values of the linewidths in the published literature. Where more than one precision measurement exists for a line, we provide the error-weighted mean of these values. Values that have no accompanying uncertainty are measured values in which no uncertainty was quoted; such values represent the only published widths for these given lines. An arithmetic mean is provided for lines with several such measurements.
Be | B | C | TiN | SiO2 | Mg | Al |
Si | Ti | Cr | Fe | Co | Ni | Cu |
Zn | Zr | Mo | Ag | Sn | W | Au |
Element | Z | Line(s) | Line Energy (keV) Bearden | Line Width (FWHM, eV) | Reference(s) |
---|---|---|---|---|---|
Be | 4 | Ka | 0.1085 | 5 | 4 |
B | 5 | - | - | - | - |
C | 6 | Ka | 0.277 | 7.8 | 4 |
TiN | - | - | - | - | - |
SiO2 | - | - | - | - | - |
Mg | 12 | Ka1,2 | 1.25360 | 1.10+-0.02 | 2 |
Kb | 1.3022 | 4 | 4 | ||
Al | 13 | Ka1,2 | 1.48670 | 0.85+-0.04 | 2 |
Kb | 1.5574 | 8 | 4 | ||
Si | 14 | - | - | - | - |
Ti | 22 | Ka1 | 4.51084 | 1.87 | 6, 7 |
Ka2 | 4.504486 | 2.34 | 6, 7 | ||
Kb1 | 4.93181 | 1.96 | 9 | ||
Kb | 4.93181 | 2.87 | 7 | ||
La | 0.4522 | 4 | 8 | ||
Cr | 24 | Ka1 | 5.41472 | 1.97+-0.03 | 3, 10, 11 |
Ka2 | 5.40551 | 2.39+-0.03 | 3, 10, 11 | ||
Kb | - | 3.05 | 7 | ||
Kb1 | 5.94671 | 2.52 | 9 | ||
La | 0.5728 | 4 | 8 | ||
Fe | 26 | Ka1 | 6.40384 | 2.55+-0.03 | 3, 10, 11 |
Ka2 | 6.39084 | 3.00+-0.04 | 3, 10, 11 | ||
Kb1 | 7.05798 | 3.59 | 9 | ||
Kb | - | 3.55+-0.07 | 11 | ||
La | 0.7050 | 3.5 | 4 | ||
Co | 27 | Ka1 | 6.93032 | 2.26+-0.05 | 3, 10 |
Ka2 | 6.91530 | 3.08+-0.05 | 3, 10 | ||
Kb1 | 7.6943 | 4.36 | 9 | ||
La | 0.7762 | 4.0 | 4 | ||
Lb | - | 4.0 | 4 | ||
Ni | 28 | Ka1 | 7.47815 | 2.25+-0.05 | 3, 5 |
Ka2 | 7.46089 | 3.15+-0.05 | 3, 5 | ||
Kb1,3 | 8.26466 | 5.44+-0.05 | 5 | ||
Kb2,5 | 8.3286 | 6.25+-0.1 | 5 | ||
La | 0.8515 | 2.7 | 4 | ||
Cu | 29 | Ka1 | 8.04778 | 2.40+-0.02 | 2, 3, 10, 11, 12, 13 |
Ka2 | 8.02783 | 2.98+-0.04 | 2, 3, 10, 11 | ||
Kb1 | 8.90529 | 5.84 | 9 | ||
Kb | - | 6.01+-0.12 | 11 | ||
La | 0.9297 | 3.7 | 4 | ||
Lb | - | 3.5 | 4 | ||
Zn | 30 | Ka1 | 8.63886 | 2.55+-0.04 | 3, 11 |
Ka2 | 8.61578 | 2.99+-0.06 | 3, 11 | ||
Kb | - | 6.38+-0.13 | 11 | ||
La1,2 | 1.0117 | 1.3+-0.1 | 14 | ||
La | - | 1.75 | 4 | ||
Lb | - | 2.15 | 4 | ||
Zr | 40 | Ka1 | 15.7751 | 5.49 | 15 |
Ka2 | 15.6909 | 5.93 | 15 | ||
La1 | 2.3027 | 1.7+-0.3 | 16 | ||
Lb1 | 2.1244 | 2.0+-0.3 | 16 | ||
Lb2,15 | 2.2194 | 6.5+-0.6 | 16 | ||
Lb3 | 2.2010 | 6.5+-0.6 | 16 | ||
Lb4 | 2.1873 | 5.9+-0.6 | 16 | ||
Lb6 | 2.3027 | 6+-1 | 16 | ||
Lg5 | 2.2551 | 7+-1 | 16 | ||
Le | 1.87654 | 8+-1 | 16 | ||
Ll | 1.79201 | 8.6+-0.8 | 16 | ||
Mz | 0.1511 | 2.06 | 17 | ||
Mo | 42 | Ka1 | 17.47934 | 6.42 | 15 |
Ka2 | 17.3743 | 6.66 | 15 | ||
Mz | 0.1926 | 3.05 | 17 | ||
Ag | 47 | Ka1 | 22.16292 | 8.6+-0.4 | 18 |
Ka2 | 21.9903 | 8.9+-0.8 | 18 | ||
La1 | 2.98431 | 2.34 | 19 | ||
La2 | 2.97821 | 2.2 | 19 | ||
Lb1 | 3.15094 | 2.4 | 19 | ||
Lb2 | - | 3.9+-0.2 | 20 | ||
Lb3 | 3.23446 | 6.6 | 19 | ||
Lb4 | 3.20346 | 5.9 | 19 | ||
Lb6 | 3.25603 | 8.6 | 19 | ||
Lb9 | 3.43917 | 5.6 | 19 | ||
Lb10 | 3.43287 | 6.0 | 19 | ||
Lg1 | 3.51959 | 4.3+-0.2 | 20 | ||
Lg2 | 3.7432 | 11.0 | 19 | ||
Lg3 | 3.7498 | 10.2 | 19 | ||
Lg5 | 3.42832 | 8.8 | 19 | ||
Ll | 2.6337 | 10.7 | 19 | ||
Le | 2.8061 | 10.8 | 19 | ||
Sn | 50 | Ka1 | 25.2713 | 11.15 | 15 |
Ka2 | 25.0440 | 12.27 | 15 | ||
Kb1 | 24.9424 | 11.7+-0.7 | 21 | ||
Kb3 | 28.4440 | 11.5+-0.7 | 21 | ||
Lb2,15 | 3.904876 | 3.2+-0.25 | 20 | ||
Lb6 | 3.7926 | 6.3+-0.6 | 20 | ||
Lg2,3 | 4.1605 | 20.3 | 22 | ||
Ll | 3.04499 | 12.0+-0.1 | 20 | ||
Mz | 0.397 | 16.4 | 17 | ||
W | 74 | Ka1 | 59.31824 | 43.2+-2.6 | 21 |
Ka2 | 57.9817 | 37.4+-5.6 | 21 | ||
Kb1 | 67.2443 | 48.6+-1.5 | 23 | ||
Kb3 | 66.9514 | 50.0+-1.5 | 23 | ||
La1 | 8.3976 | 6.61+-0.28 | 24 | ||
La2 | 8.3352 | 6.68+-0.39 | 24 | ||
Lb1 | 9.67235 | 7.33+-0.30 | 24 | ||
Lg1 | 11.2859 | 13.28+-0.72 | 24 | ||
Lb2 | 9.9615 | 9.26+-0.93 | 25 | ||
Lb3 | 9.8188 | 12.6+-1.26 | 25 | ||
Lb4 | 9.5252 | 13.2+-1.45 | 25 | ||
Ll | 7.3878 | 13.9+-2.78 | 25 | ||
Le | 8.7243 | 14.0+-2.8 | 25 | ||
Lg2 | 11.6080 | 12.1+-0.3 | 26 | ||
Lg3 | 11.6743 | 11.0+-0.3 | 26 | ||
Lg6 | 11.5387 | 5.7+-0.4 | 26 | ||
Au | 79 | Ka1 | 68.8037 | 55.5+-3.3 | 21 |
Ka2 | 66.9895 | 56.7+-8.5 | 21 | ||
La1 | 9.7133 | 7.78+-0.12 | 27 | ||
La2 | 9.6280 | 8.08+-0.16 | 27 | ||
Lb1 | 11.4423 | 8.20+-0.21 | 27 | ||
Lb2 | 11.5847 | 10.12+-0.15 | 27 | ||
Lb3 | 11.6103 | 16.48+-0.57 | 27 | ||
Lb4 | 11.2047 | 19.6+-0.9 | 26 | ||
Lg1 | 13.3817 | 10.1+-0.3 | 26 | ||
Lg2 | 13.7095 | 16.6+-0.8 | 26 | ||
Lg3 | 13.8090 | 14.9+-0.5 | 26 | ||
Lg6 | 13.7304 | 7.6+-0.6 | 26 | ||
Lg4 | 14.2996 | 18.6 | 28 | ||
Lg8 | 13.6260 | 9.5 | 28 | ||
Lg5 | 12.9743 | 15.2 | 28 | ||
Lb9 | 12.1474 | 12.1 | 28 | ||
Lb10 | 12.0617 | 13.1 | 28 | ||
Lb5 | 11.9163 | 7.6 | 28 | ||
Lb7 | 11.8106 | 13.1 | 28 | ||
Lb15 | 11.5667 | 11.0 | 28 | ||
Lb6 | 11.1602 | 16.3 | 28 | ||
Le | 10.3083 | 19.3 | 28 | ||
Ll | 8.4939 | 19.8 | 28 |
Number | References | Comments |
---|---|---|
1 | Bearden, J. A.,"X-Ray Wavelengths," Rev. Mod. Phys. 39, 78 (1967) | Database of measured characteristic x-ray line wavelengths using a Tungsten K-a1 standard. We quote these line energies unless otherwise noted. |
2 | P. Citrin, P. M. Eisenberg, and W.C. Marra Phys Rev B 10, 1762 (1974) | Taken from secondary emission spectra unless otherwise noted, uncertainties stated. |
3 | P. L. Lee and S. I. Salem Phys Rev A 10, 2027 (1974) | This reference provides data associated with z=23-32. Metallic targets, uncertainties stated. |
4 | Faessler, A., "Roentgenspektrum und Bindungszustand", in Landolt-Boerstein: Zahlenwerte und Funktionen, 6. Auflage, 1.Band, 4.Teil, Berlin: Springer-Verlag, 1955 | Data included in Mike Huang's (SAO) compliation. |
5 | H. Sorum and J. Bremer J. Phys F. 12, 2721 (1982) | This reference studies the K-emission band of Ni using a metal target and states uncertainties. |
6 | L. Parratt Phys Rev 44, 695 (1933) | The data was taken from metallic targets and corrected for overlapping. No uncertainties stated. |
7 | H. H. Roseberry and J. A. Bearden Phys Rev 50, 204 (1936) | The data was taken from metallic targets and has a brief qualitative discussion on measurment errors. |
8 | Tomboulian, D. H., "Experimental methods of Soft X-Ray Spectroscopy and the Valence Band Spectra of the LIght Elements" in Handbuch der Physik, Berlin: Springer-Verlag, 1957 | Data included in Mike Huang's (SAO) compliation. |
9 | G. Brogden Arfiv Fysik 23, 219 (1962) | Metallic targets? |
10 | H. Sorum J. Phys. F 17, 417 (1987) | Metallic targets, states uncertainties. |
11 | L. Obert and J. A. Bearden Phys Rev 54, 1000 (1938) | The uncertainty for Ka1 lines is 3% and for Ka2 and Kb 4%. Fluorescing radiation instead of electron bombardment, metallic targets. |
12 | M. H. Heinonen, J. A. Leiro, and E. J. Suoninen Philos. Mag. B 44, 175 (1981) | Data obatined from Ref. 13, states uncertainties. |
13 | M. Deutsch and M. Hart Phys. Rev. B 26, 5558 (1982) | Cu Ka1 line, for metallic target, states uncertainty.. |
14 | J. A. Leiro X-Ray Spectrom. 16, 177 (1987) | La1,2 lines for Zn, states uncertainties. |
15 | B. G. Gokhale Ann. Phys. 7, 852 (1952) | Data for z=40, 42 - Ka1 and Ka2 lines, no uncertainties stated. |
16 | M. O. Krause, F. Wulleumier, and C. W. Nestor Jr. Phys. Rev A 6, 871 (1972) | L-lines for Zr, metallic target, states uncertainties. |
17 | J. Cooper Phys. Rev 65,155 (1944) | Includes M lines for a few elements, no stated uncertainties. |
18 | E. G. Kessler, Jr. , R. D. Deslattes, D. Girant, W. Schwitz, I. Jacobs, and O. Renner Phys. Rev A 26,2696 (1982) | States measurement uncertainties. |
19 | L. Parratt Phys. Rev 54,99 (1938) | The entire L-spectrum for Ag, including satellites. Metallic target and does not state uncertainties. |
20 | M. Ohno, P. Putila-Mantyla and G. GraeffeJ. Phys. B 17,1747(1984) | L-lines for elements of intermediate Z, for metallic targets and with uncertainties stated. |
21 | G. C. Nelson and B. G. SaundersJour. Physique (Paris) 32,C4-97 (1971) | Data for K-lines for Z > 50, from metallic targets and with uncertainties. |
22 | Ekstig and Kallne E 1969 private communication quoted in K D Sevier 1972Low-Energy Electron Spectrometry (New York: Wiley-Interscience) p 220 | Data obtained from Ref. 20. |
23 | F. K. Richtmeyer and S. W. BarnesPhys. Rev. 35 476 (1930) | This paper discusses measurement uncertainties and was one of the first papers to correct for instrumental effects. |
24 | B. Gokhale, S. N. Shukla, and R. N. SrivastavaPhys. Rev. A 28 858 (1983) | L-lines of W metallic target, with uncertainties. |
25 | S. I. Salem and P. L. LeePhys. Rev. A 10 2033 (1974) | L-lines from metallic targets of rare earth elements and W, with uncertainties. |
26 | J. CooperPhys. Rev. 61 234 (1942) | L-lines from Yb-Tl metallic targets, including W and Au, with uncertainties. |
27 | P. Amorium, L. Salgueiro, F. Parente and J. G. FerreiraJ. Phys B 21 3851(1988) | L-lines from Ir,Pt, Au,Th and U metallic targets, with uncertainties. |
28 | F. K. Richtmeyer, S. W. Barnes and E. RambergPhys Rev 45 843(1934) | L-lines of Au from a metallic target, with no uncertainties quoted. |
29 | S. I. Salem and P. L. Lee At. Data and Nuc. Data Tables 18 233-241 (1976) | This reference provides a least-square fit to the existing data for K and L lines from z=20 to z=96. |
30 | M.O. Krause and J.H. Oliver J. Phys. Chem. Ref. Data 8 329-338 (1979) | A catalog of linewidths for Z = 10-110 derived from level widths. |
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